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Experimental balance studies indicate that urinary riboflavin excretionary rates increase slowly with increasing intakes until the point of tissue saturation, after which any further increase of riboflavin intake leads to a sharp elevation of the excretion rate, as shown in Figure 20b.3

PloS One (2017) 12:e0187189

Avila, M., Mora Snchez, M

However, because it is a sulfur-based compound, some people may experience mild digestive upset or notice a slight sulfur-like smell

Plus, there's the contamination risk of mixing things up on your own, outside the clean rooms that pharma normally uses