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The sulfhydryl group on the cysteine residue, which is the reactive core of glutathiones antioxidant function, oxidises rapidly under gastric conditions

doi:10.1042/bj2860637

If you see an air bubble, flick the side of the syringe

[Phosphorylation and activation of glutathione peroxidase and [PMID: 3698805] Laboratory literature summary: [Phosphorylation and activation of glutathione peroxidase and glutathione-S-transferase by cAMP-dependent protein kinase]

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However, once diagnosed it presents a difficult management problem in patients suffering from pernicious anemia, as there is no substitute