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Since superoxide anion cannot diffuse across the inner mitochondrial membrane it remains in the matrix which allows it to react with Fe-S groups in mitochondrial proteins resulting in the liberation of ferrous (Fe 2+ ) iron
Secondly, the synthesis of glutathione (GSH) is impaired, leading to the functional loss of its dependent antioxidant enzyme, glutathione peroxidase 4 (GPX4)
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doi: 10.1111/cpr.13478 40 JiangJHuangDJiangYHouJTianMLiJet al
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