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They are grouped as a research convenience, allowing researchers to work with a consistent, standardised composition and reducing variability associated with separate sample preparation in the laboratory
Electrospray ionization is an energetic environment for a coordination compound, and a metal-peptide complex can dissociate in the source, so what is observed may be the free tripeptide rather than the intact complex
The result: recurring reports of severe injection site infections, systemic infections, and even sepsis from contaminated peptides
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