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The prodrug conjugate showed tumor-selective release of drug and allowed fate of system to be followed by two complementary imaging techniques, i.e., off-on fluorescence enhancement (fluorescent DOX unit) and a magnetic resonance imaging (paramagnetic Gd 3+ -texaphyrin moiety)

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Thermodynamic studies reveal that MT3 binds Cu + through enthalpy-driven processes and Zn + via entropy-driven mechanisms, forming Cu 4 thiolate clusters