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References van der Poll, T., van de Veerdonk, F

Im not sure if its related, but the timing seems to coincide. While the exact mechanism behind the link between glutathione and headaches is not yet fully understood, it is thought to be related to changes in blood flow and intracranial pressure

1 2 N -acetyl-L-cysteine is a safe and effective precursor of cysteine"

A plausible explanation could be a reorientation of Lys105 towards GS resulting in a decreased stabilization of the active site thiolate as a leaving group

Observational data shows lower levels of reduced glutathione in darker skin compared to lighter skin [1][60]

& Roberts, E