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They are not interchangeable, and the comparison is not symmetrical
NAD+ is required for ATP production, and topping up a declining pool is the rationale [1]
This cyanocobalamin complex is then excreted in the urine, thereby detoxifying the cyanide and restoring cellular respiratory function
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5-Amino-1MQ is an investigational small-molecule enzyme inhibitor studied only in cell and rodent models
The same source also indicates that injectable B12 reliably restores levels when oral absorption is impaired
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